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EUROPEAN
MICRO and
NANO SYSTEMS 2004 First Issue |

-conjugated molecules can be realized using mechanically controlled break junctions to couple thiol end groups of the molecules to two gold electrodes.
We have investigated transport through
-conjugated molecules which differ by their spatial symmetry and
-conjugated connectivity.
The current voltage characteristics (IVs) of the metal-molecule-metal system reflect the spatial symmetry and topology of the molecules with respect to the direction of current flow indicating that transport occurs indeed through single molecules.
Fluctuations in the IVs are a manifestation of the variation of level spacings of the system, which depend crucially on the bonding between thiol end groups and Au electrodes.
Controlled chemical alteration of
-conjugation offers the possibility to taylor the electronic transport through single molecules. 
Copyright © 2004 Laboratoire TIMA.
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